Processing and Ductile-Brittle Transitions in PM Manganese Steels

YesBrittleness in manganese steels can be associated with processing in a "wet¿ [micro]climate resulting in the formation of continuous oxide networks. The formation of these networks can be prevented by sintering in an atmosphere, also ¿local¿ in a semiclosed container, adhering to the Ellingham-Richardson oxide reduction criteria. When this requirement is satisfied, however, further types of ductile ¿ brittle transitions are observed. Rapid cooling, typically above 40°C/min, produces enough martensite to render Fe-(3-4)Mn-(0·6-0·7)C material macroscopically brittle. Quenched and conventionally tempered structures remain brittle. It is tentatively suggested that segregation of minor alloying/tramp element(s), as in cast materials, is responsible for this temper embrittlement. To overcome it, heat treatment at a temperature no higher than 200°C, recovery/stress relief, is recommended

Densification by cold re-pressing of low-carbon managese steels

YesObtaining closed porosity, i.e. densities >7.4 g.cm-3, is a major target in PM development. To increase density, strength and surface hardness of low-carbon PM steels: cold and warm compaction, sintering and slow cooling through the ferrite transformation region, followed by cold repressing and surface hardening were investigated. The slow cooling resulted in soft, ferritic, microstructure amenable to cold resizing. Repressing at 700-900 MPa densified the samples to ~7.6 g.cm-3. Mechanical properties, after repressing and surface hardening, are characterised by appreciable plasticity following macroscopic yielding at stresses of 400-1200 MPa. Reference is made to possible further increases in strength by incorporation of small additions of clean, fine Mn containing master alloy into the powder mix. Results were verified industrially on hollow cylinders made from Fe-0.5Mo or Fe-1.5Cr-0.2Mo base powders

The Use of a Solid Hydrocarbon as a Graphite Substitute for Astaloy CrM Sintered Steel

YesAbstract Höganäs Astaloy CrM powder was used to prepare mixtures with 0.3-1.6 % carbon contents, both with and without 1 wt.% manganese additions. The carbon was added in three ways: as a graphite powder, as a solid CnHm hydrocarbon powder, and as a mixture of both. Green compacts were pressed at 300 - 800 MPa and sintered isothermally at temperatures in the range 1170 - 1295°C under flowing high purity nitrogen or nitrogen/hydrogen (9:1) atmosphere. Compressibility of the powder mixtures was investigated. Carbon loss occurring during sintering was carefully monitored. Sintering behaviour of numerous combinations of carbon content was investigated by dilatometry. For high carbon contents and high sintering temperatures, densification resulted from controlled generation of a liquid phase. Advantages of using solid hydrocarbon as a carbon donor and of Mn addition in powder metallurgy processing of steels are indicated

Distributional Impact of U.S. Farm Commodity Programs: Accounting for Alternative Farm Household Typologies

Agricultural households adjust to policy changes through market mechanisms by altering: their production mix, labor input, and on- and off-farm investments. Because of the significant heterogeneity among farms in the US agricultural sector, various types of farm households respond to the same policy change in significantly different ways. The parameters used to classify farm households into different typologies may also play a significant role in the interpretation of observed effects of policy changes. This paper, using a highly disaggregated U.S. Computable General Equilibrium (CGE) model, analyzes the distributional impacts of policy changes involving price-contingent government payments on alternative U.S. farm household typologies. We find that farm households do vary their responses to an elimination of price-contingent support based on location, production specialty, and farm categorization.Agricultural and Food Policy,

Microstructure and mechanical properties of sintered (2-4)Mn-(0¿6.-0¿8)C steels

YesMechanical properties of 2¿4% manganese PM steels were determined in tension and in bending following laboratory sintering in dry, hydrogen rich atmospheres. Young's modulus determined by an extensometric technique was about 115 GPa; when measured by an ultrasonic method it was about 153 GPa, in accordance with the`law of mixtures¿. The microstructures, significantly devoid of oxide networks, were predominantly pearlitic, but frequently with variability for specimens similarly processed, resulting in appreciable variations in the stresses for macroscopic yielding and fracture. The majority of the experiments were conducted on 3 and 4Mn¿0·6C alloys and for these R0·1 was in the range 275¿500 MPa, tensile strength (TS) 300¿600 MPa, and (apparent) transverse rupture strength (TRS) 640¿1260 MPa. Statistical techniques were employed to analyse the data. When careful control of processing was maintained, the Weibull modulus was highest, at about 17, for TS of furnace cooled specimens, and lowest, about 6, for TRS of the rapidly cooled specimens. In order to interpret the significant differences between the TRS and the TS values, both apparently measuring the critical stress for cracking after strains of up to 7%, a two stage normalising technique for TRS was adopted. By taking account of the plastic strains preceding failure, the elastic`strength of materials¿ formula was modified to allow true fracture stresses to be calculated. It was also postulated that failure was initiated from a population of flaws of variable size and then the `normalised¿ bend strengths, smaller than TRSs, were shown to correspond well with TSs. It is suggested that this combined plasticity correction and Weibull analysis approach, which has a sound scientific basis, should be employed to interpret bend test data in preference to empirical correlations between TS and TRS

Sintering microstructure and mechanical properties of PM manganese-molybdenum steels

YesThe effects of 0·5 wt-%Mo addition on the processing, microstructure, and strength of PM Fe¿3·5Mn¿0·7C steel are described. Water atomised and sponge irons, Astaloy 1·5Mo, milled ferromanganese, and graphite were the starting powders. During sintering in 75H2 /25N2 or pure hydrogen the dewpoint was controlled and monitored; in particular the effects of improving it from -35 to -60°C were investigated. Faster heating rates (20 K min-1), sufficient gas flowrates, milling the ferro alloy under nitrogen, a low dewpoint (<-60°C), and a getter powder can all contribute to the reduction or prevention of oxidation of the manganese, in particular formation of oxide networks in the sintered steels. For 600 MPa compaction pressure densities up to 7·1 g cm-3 were obtained; these were not significantly affected by sintering at temperatures up to 1180°C. The sintered microstructures were sensitively dependent on the cooling rate. Irrespective of the presence of Mo, slow furnace cooling at 4 K min-1 resulted in mainly pearlitic structures with some ferrite and coarse bainite, whereas fast cooling at 40 K min-1 produced martensite and some retained austenite, very fine pearlite, bainite, and some ferrite. Young's modulus, determined by tensile and ultrasonic tests, was in the range 110¿155 GPa. Sintering with -60°C dewpoint resulted in tensile and transverse rupture strengths of420 and 860 MPa for the Mn steel, rising to 530 and1130 MPa as a result of the Mo addition. This contrasts with strength decreases observed when processing included use of high oxygen containing ferromanganese and sintering with -35°C dewpoint

Serious Economic Pests of Coffee That May Accidentally be Introduced to Hawai'i

The purpose of this publication is to provide information about serious diseases and pests of coffee not present in the Hawaiian Islands that can be accidentally introduced on or in coffee berries brought in for seed purposes. Particularly, we focus on those diseases and pests that could be a threat to coffee production in Hawai'i. The publication is designed to serve as a reference for growers, county agents, consultants, researchers, and quarantine personnel